Modeling pesticides and ecotoxicological risk assessment in an intermittent river using SWAT.

The present work aimed to predict the fate of two pesticides, copper (Cu) and glyphosate in a Mediterranean basin with an intermittent river and to assess the ecotoxicological risk related to their presence in water bodies coupling field measurements of streamflow and pesticide concentrations, and an eco-hydrological model. The Soil and Water Assessment Tool (SWAT) model was calibrated and, subsequently used to assess predicted environmental concentrations of pesticides in surface waters. The ecotoxicological risk related to the presence of Cu and glyphosate in surface water was assessed at the reach scale by using the Toxicity to Exposure Ratio approach (TER). Measurements of glyphosate concentrations (< 0.5 µg l-1) exceeded the maximum European threshold of environmental quality standards for pesticides (EQS) of 0.1 µg l-1. High concentrations of glyphosate were predicted in the wet season and in September, when glyphosate is mostly used in vineyards and olive grove productions. Acute risk (TER < 100) associated with the presence of glyphosate was detected for several reaches. High concentrations of Cu (< 6.5 µg l-1), mainly used as a fungicide in vineyards, were predicted in several river reaches. The results of the ecotoxicological risk assessment revealed that November and January were the critical months during which most of the river reaches showed a chronic risk associated with the presence of Cu.

Ecological flow in southern Europe: Status and trends in non-perennial rivers.

The concept of environmental flows (E-Flows) describes the streamflow that is necessary to maintain river ecosystems. Although a large number of methods have been developed, a delay was recorded in implementing E-Flows in non-perennial rivers. The general aim of the paper was to analyse the criticalities and the current state of implementation of the E-Flows in non-perennial rivers of southern Europe. The specific objectives were to analyse (i) the European Union (EU) and national legislation on E-Flows, and (ii) the methodologies currently adopted for setting E-Flows in non-perennial rivers in the EU Member States (MSs) of the Mediterranean Region (Spain, Greece, Italy, Portugal, France, Cyprus, and Malta). From the analysis of national legislations, it is possible to acknowledge a step forward toward regulatory unification at the European level, on the subject of E-Flows and more generally toward the protection of aquatic ecosystems. The definition of E-Flows, for most countries, has abandoned the idea of a regime of constant and minimal flow, but it recognizes the importance of the biological, and chemical-physical aspects connected to it. From the analysis of the E-Flows implementation through the review of the case studies, one can surmise that in non-perennial rivers the E-Flows science is still an emerging discipline. The limited availability of hydrological, hydraulic, and biological data as well as the restricted economic resources allocated for managing non-perennial rivers are the main causes of the delay in the E-Flows implementation in MSs. The results of the present study may contribute in setting an E-Flow regime in non-perennial rivers.

Soil erosion modelling: A bibliometric analysis.

Soil erosion can present a major threat to agriculture due to loss of soil, nutrients, and organic carbon. Therefore, soil erosion modelling is one of the steps used to plan suitable soil protection measures and detect erosion hotspots. A bibliometric analysis of this topic can reveal research patterns and soil erosion modelling characteristics that can help identify steps needed to enhance the research conducted in this field. Therefore, a detailed bibliometric analysis, including investigation of collaboration networks and citation patterns, should be conducted. The updated version of the Global Applications of Soil Erosion Modelling Tracker (GASEMT) database contains information about citation characteristics and publication type. Here, we investigated the impact of the number of authors, the publication type and the selected journal on the number of citations. Generalized boosted regression tree (BRT) modelling was used to evaluate the most relevant variables related to soil erosion modelling. Additionally, bibliometric networks were analysed and visualized. This study revealed that the selection of the soil erosion model has the largest impact on the number of publication citations, followed by the modelling scale and the publication's CiteScore. Some of the other GASEMT database attributes such as model calibration and validation have negligible influence on the number of citations according to the BRT model. Although it is true that studies that conduct calibration, on average, received around 30% more citations, than studies where calibration was not performed. Moreover, the bibliographic coupling and citation networks show a clear continental pattern, although the co-authorship network does not show the same characteristics. Therefore, soil erosion modellers should conduct even more comprehensive review of past studies and focus not just on the research conducted in the same country or continent. Moreover, when evaluating soil erosion models, an additional focus should be given to field measurements, model calibration, performance assessment and uncertainty of modelling results. The results of this study indicate that these GASEMT database attributes had smaller impact on the number of citations, according to the BRT model, than anticipated, which could suggest that these attributes should be given additional attention by the soil erosion modelling community. This study provides a kind of bibliographic benchmark for soil erosion modelling research papers as modellers can estimate the influence of their paper.

Soil erosion modelling: A global review and statistical analysis.

To gain a better understanding of the global application of soil erosion prediction models, we comprehensively reviewed relevant peer-reviewed research literature on soil-erosion modelling published between 1994 and 2017. We aimed to identify (i) the processes and models most frequently addressed in the literature, (ii) the regions within which models are primarily applied, (iii) the regions which remain unaddressed and why, and (iv) how frequently studies are conducted to validate/evaluate model outcomes relative to measured data. To perform this task, we combined the collective knowledge of 67 soil-erosion scientists from 25 countries. The resulting database, named 'Global Applications of Soil Erosion Modelling Tracker (GASEMT)', includes 3030 individual modelling records from 126 countries, encompassing all continents (except Antarctica). Out of the 8471 articles identified as potentially relevant, we reviewed 1697 appropriate articles and systematically evaluated and transferred 42 relevant attributes into the database. This GASEMT database provides comprehensive insights into the state-of-the-art of soil- erosion models and model applications worldwide. This database intends to support the upcoming country-based United Nations global soil-erosion assessment in addition to helping to inform soil erosion research priorities by building a foundation for future targeted, in-depth analyses. GASEMT is an open-source database available to the entire user-community to develop research, rectify errors, and make future expansions.

Using water footprint concepts for water security assessment of a basin under anthropogenic pressures.

The evaluation of water shortages and pollution levels is crucial for watershed management and sustainable development. This paper proposes a water footprint (WF) sustainability assessment approach to analyse water security in a river basin under human pressures. The methodology involves a comprehensive assessment of the current water security at different spatial and temporal levels, and identifies suitable response formulations to achieve sustainability. Field surveys and measurements (streamflow, water quality) were carried out, and the Soil and Water Assessment Tool model was used for assessing water balance components and water quality. The study was carried out in the Canale d'Aiedda river basin (Taranto, Italy), which is part of the 'area of environmental crisis' of Taranto, which requires remediation of surface water, groundwater, soil and subsoil. Considering all the anthropogenic activities in the basin, including agriculture and the treated effluent disposed of via wastewater treatment plants (WWTPs), the average WF was 213.9 Mm3 y-1, of which 37.2%, 9.2% and 53.6% comprised respectively for WFgreen, WFblue and WFgrey. The WF sustainability assessment revealed that pollution was the main factor affecting surface water security. In particular, point sources contributed with 90% to the total WFgrey, and lower pollutant thresholds should be fixed for effluent from WWTPs in order to increase water quality of the receiving water body. In addition, for assuring water security the extension of the natural areas should be increased to support biodiversity in the river basin and soil management strategies should be improved to allow more water to be retained in the soil and to reduce nutrients in surface runoff. This study demonstrates that the WF sustainability assessment is a feasible approach for integrated water resources management, as well as offering a much broader perspective on how water security can be achieved in a Mediterranean basin affected by multiple anthropogenic stressors.

Coupling the water footprint accounting of crops and in-stream monitoring activities at the catchment scale.

In this work, a simple approach for calibrating the water footprint (WF) accounting of crops with in-stream measurements at the catchment scale was developed. The green and blue components of the WF were evaluated by performing a soil-water balance at a 10-day time-interval. The surface runoff was calibrated based on continuous streamflow measurements. Meanwhile, the grey component of the WF related to nitrogen use was quantified by means of the results from the in-stream monitoring activities. The methodology can be applied to any catchment where soil, land use, weather, agricultural practices, nitrogen balance and stream data are available. This methodological approach can support local authorities in the decision-making process for effective agricultural policy setting and water planning. •The WF accounting for an agricultural catchment is coupled with surface-water monitoring results•The green and blue WF are assessed by performing a soil-water balance•Surface runoff and grey water accounts are based on in-stream monitoring activities.

Characterising the hydrological regime of an ungauged temporary river system: a case study.

Temporary streams are characterised by specific hydrological regimes, which influence ecosystem processes, groundwater and surface water interactions, sediment regime, nutrient delivery, water quality and ecological status. This paper presents a methodology to characterise and classify the regime of a temporary river in Southern Italy based on hydrological indicators (HIs) computed with long-term daily flow records. By using a principal component analysis (PCA), a set of non-redundant indices were identified describing the main characteristics of the hydrological regime in the study area. The indicators identified were the annual maximum 30- and 90-day mean (DH4 and DH5), the number of zero flow days (DL6), flow permanence (MF) and the 6-month seasonal predictability of dry periods (SD6). A methodology was also tested to estimate selected HIs in ungauged river reaches. Watershed characteristics such as catchment area, gauging station elevation, mean watershed slope, mean annual rainfall, land use, soil hydraulic conductivity and available water content were derived for each site. Selected indicators were then linked to the catchment characteristics using a regression analysis. Finally, MF and SD6 were used to classify the river reaches on the basis of their degree of intermittency. The methodology presented in this paper constitutes a useful tool for ecologists and water resource managers in the Water Framework Directive implementation process, which requires a characterisation of the hydrological regime and a 'river type' classification for all water bodies.

Non-perennial Mediterranean rivers in Europe: Status, pressures, and challenges for research and management.

Non-perennial rivers and streams (NPRS) cover >50% of the global river network. They are particularly predominant in Mediterranean Europe as a result of dry climate conditions, climate change and land use development. Historically, both scientists and policy makers underestimated the importance of NRPS for nature and humans alike, mainly because they have been considered as systems of low ecological and economic value. During the past decades, diminishing water resources have increased the spatial and temporal extent of artificial NPRS as well as their exposure to multiple stressors, which threatening their ecological integrity, biodiversity and ecosystem services. In this paper, we provide a comprehensive overview of the structural and functional characteristics of NPRS in the European Mediterranean, and discuss gaps and problems in their management, concerning their typology, ecological assessment, legislative and policy protection, and incorporation in River Basin Management Plans. Because NPRS comprise highly unstable ecosystems, with strong and often unpredictable temporal and spatial variability - at least as far as it is possible to assess - we outline the future research needs required to better understand, manage and conserve them as highly valuable and sensitive ecosystems. Efficient collaborative activities among multidisciplinary research groups aiming to create innovative knowledge, water managers and policy makers are urgently needed in order to establish an appropriate methodological and legislative background. The incorporation of NPRS in EU-Med River Basin Management Plans in combination with the application of ecological flows is a first step towards enhancing NPRS management and conservation in order to effectively safeguard these highly valuable albeit threatened ecosystems.

Soil amendment with olive mill wastes: impact on groundwater.

Two sets of soil lysimeters were amended with solid and liquid olive mill wastes and the composition of leachate was analysed. Five treatments were carried out using: olive mill wastewater (OMW) at two different rates (80 and 320 m(3)/ha); OMW pre-treated by catalytical digestion with MnO2; compost obtained by exhausted olive pomace; freshwater as the control. Electric conductivity, pH, potassium, total polyphenols and nitrates were monitored in the leachate as indexes of potential groundwater contamination. The study demonstrated that the impact of all the selected amendments on groundwater was the minimum. OMW was safely applied to soil even at four times the rate allowed by the Italian law, and pre-treatment by catalytical digestion was not necessary to further reduce the impact on groundwater. The application of olive pomace compost was equally safe.